oVirt currently doesn't allow you to upload ISO's over its web interface - you'll need to use the cli to do this.
If you wish to upload an ISO to an ISO storage domain you should issue you should issue:
engine-iso-uploader --iso-domain <storage-domain-name> upload <path-to-iso>
If you wish to upload an ISO to an ISO storage domain you should issue you should issue:
engine-iso-uploader --iso-domain <storage-domain-name> upload <path-to-iso>